Ray shadows
From PyMolWiki
OVERVIEW
The ray_shadows setting determines whether or not PyMOL will ray trace shadows. This is also related to the ray_shadow setting.
SYNTAX
# turn on ray traced shadows set ray_shadows, on set ray_shadows, 1 # turn off ray traced shadows set ray_shadows, off set ray_shadows, 0
EXAMPLES
To illustrate the difference, look at the two following images:

